Alexander Ryazantsev's 35-yard rocket gave the Russians the lead in the Gro
up F encounter - and left Barca trailing for the first time this season.
Zlatan Ibrahimovic levelled in the 48th minute, controlling the ball on his chest and firing home via a post, but there was another twist to come as Gokdeniz Karadeniz grabbed a 73rd-minute winner.
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Another major upset looked on the cards at the San Siro as Dynamo Kiev twice led against Inter Milan only for Jose Mourinho's men to fight back to draw 2-2.
Taras Mykhalyk put Dynamo Kiev in front after five minutes and Lucio powered a header into his own net to restore their lead after Dejan Stankovic had levelled.
But Walter Samuel headed in at the right end two minutes after the break to make it 2-2.
Barca, Rubin and Dynamo are now all level on four points, with Inter bottom of the pool on three.
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TUESDAYS CHAMPIONS LEAGUE FINAL SCORES
Champions League - Group E
FT Debrecen 3 - 4 Fiorentina
FT Liverpool 1 - 2 Lyon
Champions League - Group F
FT Barcelona 1 - 2 Rubin Kazan
FT Inter Milan 2 - 2 Dynamo Kyiv
Champions League - Group G
FT Rangers 1 - 4 Unirea Urziceni
FT Stuttgart 1 - 3 Sevilla
Champions League - Group H
FT AZ Alkmaar 1 - 1 Arsenal
FT Olympiakos Piraeus 2 - 1 Standard Liege
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CHAMPIONS LEAGUE GROUP STANDINGS
Clubs Pld W D L GF A Pts
Olympique Lyon 3 3-0-0 7:1 9
ACF Fiorentina 3 2-0-1 6:4 6
Liverpool FC 3 1-0-2 2:4 3
Debreceni VSC 3 0-0-3 3:9 0
Clubs Pld W D L GF A Pts
FC Barcelona 3 1-1-1 3:2 4
FC Dynamo Kyiv 3 1-1-1 5:5 4
FC Rubin Kazan 3 1-1-1 4:5 4
FC Inter Milano 3 0-3-0 3:3 3
Clubs Pld W D L GF A Pts
Sevilla FC 3 3-0-0 9:2 9
Unirea Urziceni 3 1-1-1 5:4 4
VfB Stuttgart 3 0-2-1 3:5 2
Rangers FC 3 0-1 2 3:9 1
Clubs Pld W D L GF A Pts
Arsenal FC 3 2-1-0 6:3 7
Olympiacos FC 3 2-0-1 3:3 6
AZ Alkmaar 3 0-2-1 2:3 2
Standard Liege 3 0-1 2 4:6 1
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